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IF5–pyridine–HF: air- and moisture-stable fluorination reagent

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Title: IF5–pyridine–HF: air- and moisture-stable fluorination reagent
Authors: Hara, Shoji Browse this author →KAKEN DB
Monoi, Miki Browse this author
Umemura, Ryosuke Browse this author
Fuse, Chiaki Browse this author
Keywords: IF5-pyridine-HF
Air- and moisture-stable solid
Fluorination reagent
Desulfurizing-fluorination
Issue Date: 9-Dec-2012
Publisher: Elsevier
Journal Title: Tetrahedron
Volume: 68
Issue: 49
Start Page: 10145
End Page: 10150
Publisher DOI: 10.1016/j.tet.2012.09.104
Abstract: IF5–pyridine–HF, an air- and moisture-stable solid, can be used as a fluorination reagent for the introduction of fluorine atoms to the α-position of the sulfur atom in sulfides. The desulfurizing–fluorination reactions of benzylic sulfides, thioacetals, and 2-(methylthio)-1,3-dithiane derivatives were also performed using this reagent.
Type: article (author version)
URI: http://hdl.handle.net/2115/50354
Appears in Collections:工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 原 正治

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