HUSCAP logo Hokkaido Univ. logo

Hokkaido University Collection of Scholarly and Academic Papers >
Graduate School of Science / Faculty of Science >
Peer-reviewed Journal Articles, etc >

Crystal Structure of Ruthenium Phthalocyanine with Diaxial Monoatomic Ligand: Bis(Triphenylphosphine) Iminium Dichloro(Phthalocyaninato(2-)) Ruthenium(III)

This item is licensed under: Creative Commons Attribution 3.0 Unported

Files in This Item:
JoC2013_486318.pdf776.26 kBPDFView/Open
Please use this identifier to cite or link to this item:http://hdl.handle.net/2115/51038

Title: Crystal Structure of Ruthenium Phthalocyanine with Diaxial Monoatomic Ligand: Bis(Triphenylphosphine) Iminium Dichloro(Phthalocyaninato(2-)) Ruthenium(III)
Authors: Yu, Derrick Ethelbhert Browse this author
Kikuchi, Akira Browse this author
Taketsugu, Tetsuya Browse this author →KAKEN DB
Inabe, Tamotsu Browse this author →KAKEN DB
Issue Date: 2013
Publisher: Hindawi Publishing Corporation
Journal Title: Journal of Chemistry
Volume: 2013
Start Page: 486318
Publisher DOI: 10.1155/2013/486318
Abstract: Axially-ligated iron phthalocyanines have been found to be good molecular conductors with giant negative magnetoresistance (GNMR) which originates from a strong intramolecular π-d interaction between the metal and phthalocyanine. Ab initio theoretical calculations showed that substitution of ruthenium into the phthalocyanine complex would result in a significant increase in the π-d interaction of the system, potentially intensifying GNMR. This paper presents the crystal preparation and X-ray structural characterization of bis(triphenylphosphine)iminium dichloro(phthalocyaninato(2-))ruthenium(III), PNP [Ru^[III](Pc^[2-])Cl2]. It is observed that [Ru^[III](Pc^[2-])Cl2] system has a symmetric planar Rupc unit with perpendicular axial ligands which results in a unidirectional and uniform solid-state arrangement, suitable for π-d interaction-based molecular conductors with potentially exceptional GNMR.
Rights: http://creativecommons.org/licenses/by/3.0/
Type: article
URI: http://hdl.handle.net/2115/51038
Appears in Collections:理学院・理学研究院 (Graduate School of Science / Faculty of Science) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 稲辺 保

Export metadata:

OAI-PMH ( junii2 , jpcoar_1.0 )

MathJax is now OFF:


 

 - Hokkaido University