An N-Linked Bidentate Phosphoramidite Ligand (N-Me-BIPAM) for Rhodium-Catalyzed Asymmetric 1,4-Addition of Arylboronic Acids to α,β-Unsaturated Ketones


Hokkaido University \| Library \| HUSCAP	Advanced Search		言語

	Home
	About HUSCAP
	Open Access Policy

	Browse by Author

Browse
	Communities & Collections

	Scholarly Journals
	Theses
	Doctoral Dissertations Listed by Graduate Schools
	Conference Procs.
	Events

	HUSCAP Senior (in Japanese)

	Societies

	Downloads (country)

For university staff
	How to post your papers to HUSCAP
	Publication of theses
	Helpline about theses publication

Open Archives Compliant

You can search our collection also at:
	Google
	Google Scholar
	CiNii
	IRDB
	OAIster
	NDLTD

Files in This Item:

Mol18-1_14-26.pdf

353.99 kB

PDF

Please use this identifier to cite or link to this item:http://hdl.handle.net/2115/52050

Title:	An N-Linked Bidentate Phosphoramidite Ligand (N-Me-BIPAM) for Rhodium-Catalyzed Asymmetric 1,4-Addition of Arylboronic Acids to α,β-Unsaturated Ketones
Authors:	Yamamoto, Yasunori Browse this author →KAKEN DB
	Kurihara, Kazunori Browse this author
	Takahashi, Yoshinori Browse this author
	Miyaura, Norio Browse this author →KAKEN DB
Keywords:	asymmetric conjugate addition
	rhodium catalyst
	bidentate phosphoramidite ligand
Issue Date:	Jan-2013
Publisher:	MDPI
Journal Title:	Molecules
Volume:	18
Issue:	1
Start Page:	14
End Page:	26
Publisher DOI:	10.3390/molecules18010014
Abstract:	A new bidentate phosphoramidite (N-Me-BIPAM) based on Shibasaki's N-linked BINOL was synthesized. This ligand appears to be highly effective for rhodium-catalyzed asymmetric conjugated addition of arylboronic acids to α,β-unsaturated enones. The reaction of ortho-substituted arylboronic acid with acyclic and cyclic enones provides the corresponding products in good yields and enantioselectivities.
Rights:	http://creativecommons.org/licenses/by/3.0/
Type:	article
URI:	http://hdl.handle.net/2115/52050
Appears in Collections:	工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 山本靖典

OAI-PMH ( junii2 , jpcoar_1.0 )

- Hokkaido University