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An N-Linked Bidentate Phosphoramidite Ligand (N-Me-BIPAM) for Rhodium-Catalyzed Asymmetric 1,4-Addition of Arylboronic Acids to α,β-Unsaturated Ketones

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Title: An N-Linked Bidentate Phosphoramidite Ligand (N-Me-BIPAM) for Rhodium-Catalyzed Asymmetric 1,4-Addition of Arylboronic Acids to α,β-Unsaturated Ketones
Authors: Yamamoto, Yasunori Browse this author →KAKEN DB
Kurihara, Kazunori Browse this author
Takahashi, Yoshinori Browse this author
Miyaura, Norio Browse this author →KAKEN DB
Keywords: asymmetric conjugate addition
rhodium catalyst
bidentate phosphoramidite ligand
Issue Date: Jan-2013
Publisher: MDPI
Journal Title: Molecules
Volume: 18
Issue: 1
Start Page: 14
End Page: 26
Publisher DOI: 10.3390/molecules18010014
Abstract: A new bidentate phosphoramidite (N-Me-BIPAM) based on Shibasaki's N-linked BINOL was synthesized. This ligand appears to be highly effective for rhodium-catalyzed asymmetric conjugated addition of arylboronic acids to α,β-unsaturated enones. The reaction of ortho-substituted arylboronic acid with acyclic and cyclic enones provides the corresponding products in good yields and enantioselectivities.
Rights: http://creativecommons.org/licenses/by/3.0/
Type: article
URI: http://hdl.handle.net/2115/52050
Appears in Collections:工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 山本 靖典

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