Cross-Coupling Reaction with Lithium Methyltriolborate


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Title:	Cross-Coupling Reaction with Lithium Methyltriolborate
Authors:	Yamamoto, Yasunori Browse this author →KAKEN DB
	Ikizakura, Kazuya Browse this author
	Ito, Hajime Browse this author →KAKEN DB
	Miyaura, Norio Browse this author →KAKEN DB
Keywords:	cross-coupling reaction
	palladium catalyst
	methyltrioolborate
Issue Date:	Jan-2013
Publisher:	MDPI
Journal Title:	Molecules
Volume:	18
Issue:	1
Start Page:	430
End Page:	439
Publisher DOI:	10.3390/molecules18010430
Abstract:	We newly developed lithium methyltriolborate as an air-stable white solid that is convenient to handle. The good performance of this triolborate for metal-catalyzed bond-forming reactions was demonstrated in palladium-catalyzed cross-coupling reactions with haloarenes. Cross-coupling reaction of [MeB(OCH2)3CCH3]Li with aryl halides occurred in the presence of Pd(OAc)2/RuPhos complex in refluxing MeOH/H2O and the absence of bases.
Rights:	http://creativecommons.org/licenses/by/3.0/
Type:	article
URI:	http://hdl.handle.net/2115/52062
Appears in Collections:	工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 山本靖典

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