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Cross-Coupling Reaction with Lithium Methyltriolborate

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Title: Cross-Coupling Reaction with Lithium Methyltriolborate
Authors: Yamamoto, Yasunori Browse this author →KAKEN DB
Ikizakura, Kazuya Browse this author
Ito, Hajime Browse this author →KAKEN DB
Miyaura, Norio Browse this author →KAKEN DB
Keywords: cross-coupling reaction
palladium catalyst
methyltrioolborate
Issue Date: Jan-2013
Publisher: MDPI
Journal Title: Molecules
Volume: 18
Issue: 1
Start Page: 430
End Page: 439
Publisher DOI: 10.3390/molecules18010430
Abstract: We newly developed lithium methyltriolborate as an air-stable white solid that is convenient to handle. The good performance of this triolborate for metal-catalyzed bond-forming reactions was demonstrated in palladium-catalyzed cross-coupling reactions with haloarenes. Cross-coupling reaction of [MeB(OCH2)3CCH3]Li with aryl halides occurred in the presence of Pd(OAc)2/RuPhos complex in refluxing MeOH/H2O and the absence of bases.
Rights: http://creativecommons.org/licenses/by/3.0/
Type: article
URI: http://hdl.handle.net/2115/52062
Appears in Collections:工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 山本 靖典

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