Functional Group Tolerable Synthesis of Allylsilanes through Copper-Catalyzed γ-Selective Allyl-Alkyl Coupling between Allylic Phosphates and Alkylboranes


Hokkaido University \| Library \| HUSCAP	Advanced Search		言語

	Home
	About HUSCAP
	Open Access Policy

	Browse by Author

Browse
	Communities & Collections

	Scholarly Journals
	Theses
	Doctoral Dissertations Listed by Graduate Schools
	Conference Procs.
	Events

	HUSCAP Senior (in Japanese)

	Societies

	Downloads (country)

For university staff
	How to post your papers to HUSCAP
	Publication of theses
	Helpline about theses publication

Open Archives Compliant

You can search our collection also at:
	Google
	Google Scholar
	CiNii
	IRDB
	OAIster
	NDLTD

Files in This Item:

Syn44-10_1535-1541.pdf

387.1 kB

PDF

Please use this identifier to cite or link to this item:http://hdl.handle.net/2115/52717

Title:	Functional Group Tolerable Synthesis of Allylsilanes through Copper-Catalyzed γ-Selective Allyl-Alkyl Coupling between Allylic Phosphates and Alkylboranes
Authors:	Nagao, Kazunori Browse this author
	Ohmiya, Hirohisa Browse this author
	Sawamura, Masaya Browse this author →KAKEN DB
Keywords:	allylsilane
	copper
	allylic substitution
	alkylborane
	regioselectivity
Issue Date:	May-2012
Publisher:	Georg Thieme Verlag
Journal Title:	Synthesis
Volume:	44
Issue:	10
Start Page:	1535
End Page:	1541
Publisher DOI:	10.1055/s-0031-1290818
Abstract:	A copper-catalyzed γ-selective allyl-alkyl coupling between γ-silylated allylic phosphates and alkylboron compounds (alkyl-9-BBN, prepared by hydroboration of alkenes with 9-BBN-H) produced allylsilanes. The reaction tolerated various functional groups in both the alkylboranes and the allylic phosphates, and afforded functionalized allylsilanes.
Rights:	© 2012 Georg Thieme Verlag
Type:	article (author version)
URI:	http://hdl.handle.net/2115/52717
Appears in Collections:	理学院・理学研究院 (Graduate School of Science / Faculty of Science) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 大宮寛久

OAI-PMH ( junii2 , jpcoar_1.0 )

- Hokkaido University