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Direct bromination of hydrocarbons catalyzed by Li2MnO3 under oxygen and photo-irradiation conditions

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Title: Direct bromination of hydrocarbons catalyzed by Li2MnO3 under oxygen and photo-irradiation conditions
Authors: Nishina, Yuta Browse this author
Morita, Junya Browse this author
Ohtani, Bunsho Browse this author →KAKEN DB
Issue Date: 2013
Publisher: Royal Society of Chemistry
Journal Title: RSC Advances
Volume: 3
Issue: 7
Start Page: 2158
End Page: 2162
Publisher DOI: 10.1039/c2ra22197g
Abstract: A method for the direct bromination of hydrocarbons with Br2 using a ubiquitous and inexpensive catalyst is highly desirable. Herein, we report the selective monobromination of hydrocarbons in good yield using Li2MnO3 as a catalyst under irradiation with a fluorescent room light. This new catalyst can be recyclable. The effect of light was investigated using action spectra, which revealed that the reaction occurred on the surface of the catalyst.
Rights: RSC Adv., 2013,3, 2158-2162 - Reproduced by permission of The Royal Society of Chemistry (RSC)
Type: article (author version)
URI: http://hdl.handle.net/2115/53760
Appears in Collections:触媒科学研究所 (Institute for Catalysis) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 大谷 文章

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