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High density monolayer of diisocyanide on gold surface as a platform of supported Rh-catalyst for selective 1,4-hydrogenation of α,β-unsaturated carbonyl compounds

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Title: High density monolayer of diisocyanide on gold surface as a platform of supported Rh-catalyst for selective 1,4-hydrogenation of α,β-unsaturated carbonyl compounds
Authors: Jagtap, Sachin Browse this author
Kaji, Yoshinori Browse this author
Fukuoka, Atsushi Browse this author
Hara, Kenji Browse this author →KAKEN DB
Issue Date: Apr-2014
Publisher: Royal Society of Chemistry
Journal Title: Chemical Communications
Volume: 50
Start Page: 5046
End Page: 5048
Publisher DOI: 10.1039/c3cc48181f
PMID: 24714978
Abstract: A high density monolayer of diisocyanide on gold surface was utilized as a platform of supported Rh catalyst for selective 1,4-hydrogenation of α,β-unsaturated carbonyl compounds. The catalyst exhibited high turnover numbers in a range of 50 000 to 150 000 per Rh atom and showed steady catalyst performance over six recycle usages.
Rights: http://creativecommons.org/licenses/by/3.0/
Type: article
URI: http://hdl.handle.net/2115/55274
Appears in Collections:触媒科学研究所 (Institute for Catalysis) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

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