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Hokkaido University Collection of Scholarly and Academic Papers >
Graduate School of Engineering / Faculty of Engineering >
Peer-reviewed Journal Articles, etc >
Selective trifluorination of alkyl aryl sulfides using IF5
| Title: | Selective trifluorination of alkyl aryl sulfides using IF5 |
| Authors: | Ayuba, Shinichi Browse this author | | Hiramatsu, Chiharu Browse this author | | Fukuhara, Tsuyoshi Browse this author | | Hara, Shoji4 Browse this author →KAKEN DB |
| Authors(alt): | 原, 正治4 |
| Keywords: | Halogenation | | Hypervalent elements | | Migration | | Sulfides |
| Issue Date: | 6-Dec-2004 |
| Publisher: | Elsevier |
| Journal Title: | Tetrahedron |
| Volume: | 60 |
| Issue: | 50 |
| Start Page: | 11445 |
| End Page: | 11541 |
| Publisher DOI: | 10.1016/j.tet.2004.09.076 |
| Abstract: | In the reaction of IF5 with alkyl aryl sulfides in heptane under reflux conditions, the arylthio group migrated once and three fluorine atoms were selectively introduced on the alkyl chain. In order to find the reason why the reaction stopped at the trifluorination step, we examined the oxidation potentials of the starting material, a reaction intermediate, and the product, and the time course of the reactions. |
| Relation: | http://www.sciencedirect.com/science/journal/00404020 |
| Type: | article (author version) |
| URI: | http://hdl.handle.net/2115/560 |
| Appears in Collections: | 工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)
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Submitter: 原 正治
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