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Synthesis of β-Boryl-α,β-unsaturated Carbonyl Compounds via Palladium-Catalyzed Cross-Coupling Reaction of Bis(pinacolato)diboron with Vinyl Triflates

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Title: Synthesis of β-Boryl-α,β-unsaturated Carbonyl Compounds via Palladium-Catalyzed Cross-Coupling Reaction of Bis(pinacolato)diboron with Vinyl Triflates
Authors: Miyaura, Norio Browse this author →KAKEN DB
Ishiyama, Tatsuo Browse this author →KAKEN DB
Takagi, Jun Browse this author
Kamon, Akihiro Browse this author
Keywords: diboron
vinyl triflate
palladium
cross-coupling
catalysis
Issue Date: Nov-2002
Publisher: Thieme
Journal Title: Synlett
Volume: 2002
Issue: 11
Start Page: 1880
End Page: 1882
Publisher DOI: 10.1055/s-2002-34869
Abstract: Cross-coupling reaction of bis(pinacolato)diboron with -(trifluoromethanesulfonyloxy)- , -unsaturated carbonyl compounds was carried out in the presence of PdCl2(PPh3)2-2PPh3 (3 mol%) and KOPh in toluene or K2CO3 in dioxane for the synthesis of cyclic and acyclic -boryl- , -unsaturated esters, amides, and ketones in high yields.
Relation: http://www.thieme-chemistry.com/fileadmin/Thieme/Journals/Synlett/pdf/Thieme_Institutional_Repositories_Nov_2013.pdf
Type: article (author version)
URI: http://hdl.handle.net/2115/56227
Appears in Collections:工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 石山 竜生

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