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Hokkaido University Collection of Scholarly and Academic Papers >
Graduate School of Engineering / Faculty of Engineering >
Peer-reviewed Journal Articles, etc >
Synthesis of β-Boryl-α,β-unsaturated Carbonyl Compounds via Palladium-Catalyzed Cross-Coupling Reaction of Bis(pinacolato)diboron with Vinyl Triflates
| Title: | Synthesis of β-Boryl-α,β-unsaturated Carbonyl Compounds via Palladium-Catalyzed Cross-Coupling Reaction of Bis(pinacolato)diboron with Vinyl Triflates |
| Authors: | Miyaura, Norio Browse this author →KAKEN DB | | Ishiyama, Tatsuo Browse this author →KAKEN DB | | Takagi, Jun Browse this author | | Kamon, Akihiro Browse this author |
| Keywords: | diboron | | vinyl triflate | | palladium | | cross-coupling | | catalysis |
| Issue Date: | Nov-2002 |
| Publisher: | Thieme |
| Journal Title: | Synlett |
| Volume: | 2002 |
| Issue: | 11 |
| Start Page: | 1880 |
| End Page: | 1882 |
| Publisher DOI: | 10.1055/s-2002-34869 |
| Abstract: | Cross-coupling reaction of bis(pinacolato)diboron with -(trifluoromethanesulfonyloxy)- , -unsaturated carbonyl compounds was carried out in the presence of PdCl2(PPh3)2-2PPh3 (3 mol%) and KOPh in toluene or K2CO3 in dioxane for the synthesis of cyclic and acyclic -boryl- , -unsaturated esters, amides, and ketones in high yields. |
| Relation: | http://www.thieme-chemistry.com/fileadmin/Thieme/Journals/Synlett/pdf/Thieme_Institutional_Repositories_Nov_2013.pdf |
| Type: | article (author version) |
| URI: | http://hdl.handle.net/2115/56227 |
| Appears in Collections: | 工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)
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Submitter: 石山 竜生
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