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Synthesis and Photocrosslinking Reaction of N-Allylcarbamoylmethyl Cellulose Leading to Hydrogel
| Title: | Synthesis and Photocrosslinking Reaction of N-Allylcarbamoylmethyl Cellulose Leading to Hydrogel |
| Authors: | Shen, Xiande Browse this author | | Kitajyo, Yoshikazu Browse this author | | Duan, Qian Browse this author | | Narumi, Atsushi Browse this author | | Kaga, Harumi Browse this author | | Kaneko, Noriaki Browse this author | | Satoh, Toshifumi Browse this author →KAKEN DB | | Kakuchi, Toyoji8 Browse this author →KAKEN DB |
| Authors(alt): | 覚知, 豊次8 |
| Issue Date: | 2006 |
| Publisher: | Springer Berlin / Heidelberg |
| Journal Title: | Polymer Bulletin |
| Volume: | 56 |
| Issue: | 2-3 |
| Start Page: | 137 |
| End Page: | 143 |
| Publisher DOI: | 10.1007/s00289-005-0482-2 |
| Abstract: | The reaction of the carboxymethyl cellulose sodium salt (Na-CMC) (degrees of substitution (DS) = 1.2) with N-hydroxysuccinimide (Su-OH) in the presence of 1-hydroxybenzotriazole and 1-ethyl-3-(3-dimethylaminopropyl)carbodiimide (EDC) was carried out in water to obtain the Su-OH ester of carboxymethyl cellulose, Su-CMC, with the DS values of 0.19 – 1.04. N-Allylcarbamoylmethyl cellulose (Allyl-CMC), which was prepared from the reaction of Su-CMC with an excess amount of allylamine, was crosslinked by UV-irradiation. In addition, the photocrosslinked Allyl-CMC film was swollen with water to form a hydrogel having a relatively high water-swelling property, e.g., the degree of swelling (ds) was ca. 360% for Allyl-CMC with the DS of 0.93. |
| Rights: | The original publication is available at www.springerlink.com |
| Type: | article (author version) |
| URI: | http://hdl.handle.net/2115/5737 |
| Appears in Collections: | 工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)
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Submitter: 覺知 豊次
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