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Excitation temperature of a solution plasma during nanoparticle synthesis
| Title: | Excitation temperature of a solution plasma during nanoparticle synthesis |
| Authors: | Saito, Genki Browse this author →KAKEN DB | | Nakasugi, Yuki Browse this author | | Akiyama, Tomohiro Browse this author |
| Issue Date: | 28-Aug-2014 |
| Publisher: | American Institute of Physics |
| Journal Title: | Journal of Applied Physics |
| Volume: | 116 |
| Issue: | 8 |
| Start Page: | 83301 |
| Publisher DOI: | 10.1063/1.4894156 |
| Abstract: | Excitation temperature of a solution plasma was investigated by spectroscopic measurements to control the nanoparticle synthesis. In the experiments, the effects of edge shielding, applied voltage, and electrode material on the plasma were investigated. When the edge of the Ni electrode wire was shielded by a quartz glass tube, the plasma was uniformly generated together with metallic Ni nanoparticles. The emission spectrum of this electrode contained OH, H-alpha, H-beta, Na, O, and Ni lines. Without an edge-shielded electrode, the continuous infrared radiation emitted at the edge created a high temperature on the electrode surface, producing oxidized coarse particles as a result. The excitation temperature was estimated from the Boltzmann plot. When the voltages were varied at the edge-shielded electrode with low average surface temperature by using different electrolyte concentrations, the excitation temperature of current-concentration spots increased with an increase in the voltage. The size of the Ni nanoparticles decreased at high excitation temperatures. Although the formation of nanoparticles via melting and solidification of the electrode surface has been considered in the past, vaporization of the electrode surface could occur at a high excitation temperature to produce small particles. Moreover, we studied the effects of electrodes of Ti, Fe, Ni, Cu, Zn, Zr, Nb, Mo, Pd, Ag, W, Pt, Au, and various alloys of stainless steel and Cu-Ni alloys. With the exception of Ti, the excitation temperatures ranged from 3500 to 5500 K and the particle size depended on both the excitation temperature and electrode-material properties. |
| Rights: | Copyright 2014 American Institute of Physics. This article may be downloaded for personal use only. Any other use requires prior permission of the author and the American Institute of Physics. The following article appeared in Journal of Applied Physics
116, 083301 (2014) and may be found at http://dx.doi.org/10.1063/1.4894156 |
| Type: | article |
| URI: | http://hdl.handle.net/2115/57533 |
| Appears in Collections: | 工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)
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Submitter: 齊藤 元貴
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