A stereoselective method for the construction of the C8′–O–C6″ ether of nigricanoside-A: synthesis of simple models for the C20 lipid chain/galactosyl glycerol segment


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Please use this identifier to cite or link to this item:http://hdl.handle.net/2115/58265

Title:	A stereoselective method for the construction of the C8′–O–C6″ ether of nigricanoside-A: synthesis of simple models for the C20 lipid chain/galactosyl glycerol segment
Authors:	Kinashi, Naoto Browse this author
	Fujiwara, Kenshu Browse this author →KAKEN DB
	Tsunoda, Takayuki Browse this author
	Katoono, Ryo Browse this author
	Kawai, Hidetoshi Browse this author
	Suzuki, Takanori Browse this author →KAKEN DB
Keywords:	Natural product synthesis
	Monogalactosyl diacyl glycerol
	Ireland–Claisen rearrangement
	Ether lipid
	Stereoselective synthesis
Issue Date:	21-Aug-2013
Publisher:	Elsevier
Journal Title:	Tetrahedron Letters
Volume:	54
Issue:	34
Start Page:	4564
End Page:	4567
Publisher DOI:	10.1016/j.tetlet.2013.06.085
Abstract:	A method for the stereoselective construction of the C8′–O–C6″ ether of nigricanoside-A, an antimitotic natural product from the green alga Avrainvillea nigricans, has been developed based on chirality-transferring Ireland–Claisen rearrangement. The method was successfully applied to the synthesis of simple models for the C20 lipid chain/galactosyl glycerol segment of the natural product.
Type:	article (author version)
URI:	http://hdl.handle.net/2115/58265
Appears in Collections:	理学院・理学研究院 (Graduate School of Science / Faculty of Science) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 藤原憲秀

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