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Stable Hydrogen Production from Ethanol through Steam Reforming Reaction over Nickel-Containing Smectite-Derived Catalyst
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| Title: | Stable Hydrogen Production from Ethanol through Steam Reforming Reaction over Nickel-Containing Smectite-Derived Catalyst |
| Authors: | Yoshida, Hiroshi Browse this author | | Yamaoka, Ryohei Browse this author | | Arai, Masahiko Browse this author →KAKEN DB |
| Keywords: | hydrogen | | steam reforming | | ethanol | | nickel | | smectite |
| Issue Date: | Jan-2015 |
| Publisher: | Mdpi Ag |
| Journal Title: | International Journal of Molecular Sciences |
| Volume: | 16 |
| Issue: | 1 |
| Start Page: | 350 |
| End Page: | 362 |
| Publisher DOI: | 10.3390/ijms16010350 |
| Abstract: | Hydrogen production through steam reforming of ethanol was investigated with conventional supported nickel catalysts and a Ni-containing smectite-derived catalyst. The former is initially active, but significant catalyst deactivation occurs during the reaction due to carbon deposition. Side reactions of the decomposition of CO and CH4 are the main reason for the catalyst deactivation, and these reactions can relatively be suppressed by the use of the Ni-containing smectite. The Ni-containing smectite-derived catalyst contains, after H-2 reduction, stable and active Ni nanocrystallites, and as a result, it shows a stable and high catalytic performance for the steam reforming of ethanol, producing H-2. |
| Rights: | http://creativecommons.org/licenses/by/4.0/ |
| Type: | article |
| URI: | http://hdl.handle.net/2115/58427 |
| Appears in Collections: | 工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)
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Submitter: 荒井 正彦
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