Formal Nucleophilic Boryl Substitution of Organic Halides with Silylborane/Alkoxy Base System


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Please use this identifier to cite or link to this item:http://hdl.handle.net/2115/59427

Title:	Formal Nucleophilic Boryl Substitution of Organic Halides with Silylborane/Alkoxy Base System
Authors:	Yamamoto, Eiji Browse this author
	Izumi, Kiyotaka Browse this author
	Horita, Yuko Browse this author
	Ukigai, Satoshi Browse this author
	Ito, Hajime Browse this author →KAKEN DB
Keywords:	Nucleophilic boryl substitution
	Organic halides
	Silylborane
	Transition-metal-free
	Umpolung
Issue Date:	Jun-2014
Publisher:	Springer/Plenum Publishers
Journal Title:	Topics in catalysis
Volume:	57
Issue:	10-13
Start Page:	940
End Page:	945
Publisher DOI:	10.1007/s11244-014-0255-y
Abstract:	Boryl substitution of organohalides with a silylborane and alkoxy bases is described. This reaction can be applied to various functionalized aryl halides. Alkyl and alkenyl halides, and even sterically congested aryl bromides also provided the corresponding borylated products in high yields. Mechanistic studies indicated that neither trace transition-metal impurities nor aryl radical species involved in this reaction.
Rights:	The final publication is available at link.springer.com
Type:	article (author version)
URI:	http://hdl.handle.net/2115/59427
Appears in Collections:	工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 伊藤肇

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