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Carbon Nanotube Synthesis via the Calciothermic Reduction of Carbon Dioxide with Iron Additives
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| Title: | Carbon Nanotube Synthesis via the Calciothermic Reduction of Carbon Dioxide with Iron Additives |
| Authors: | Kikuchi, Tatsuya Browse this author →KAKEN DB | | Ishida, Ryoma Browse this author | | Natsui, Shungo Browse this author →KAKEN DB | | Kumagai, Takehiko Browse this author | | Ogino, Isao Browse this author →KAKEN DB | | Sakaguchi, Norihito Browse this author →KAKEN DB | | Ueda, Mikito Browse this author →KAKEN DB | | Suzuki, Ryosuke O. Browse this author →KAKEN DB |
| Keywords: | Calciothermic Reduction | | Carbon Dioxide | | Carbon Nanotube | | Molten Salt | | Onion-Like Carbon |
| Issue Date: | 2015 |
| Publisher: | Electrochemical Society |
| Journal Title: | ECS Solid State Letters |
| Volume: | 4 |
| Issue: | 9 |
| Start Page: | M19 |
| End Page: | M22 |
| Publisher DOI: | 10.1149/2.0031509ssl |
| Abstract: | The novel fabrication of multi-walled carbon nanotube (MWCNT)/cementite (Fe3C) nanocomposites was demonstrated via the calciothermic reduction of carbon dioxide (CO2) through electrolysis in molten CaCl2/CaO with iron additives at 1173 K. In this technique, CO2 generated from a graphite anode is reduced to carbon with a metallic calcium reductant formed on a graphite cathode via electrolysis in molten salt. Calciothermic reduction without iron additives resulted in the formation of onion-like carbons (OLCs) with spherical graphite layers and thin graphite sheets. In contrast, MWCNT/Fe3C nanocomposites and OLCs were successfully fabricated via calciothermic reduction with iron additives through their catalytic activities. |
| Rights: | © The Electrochemical Society, Inc. 2015. All rights reserved. Except as provided under U.S. copyright law, this work may not be reproduced, resold, distributed, or modified without the express permission of The Electrochemical Society (ECS). The archival version of this work was published in ECS Solid State Letters. | | http://creativecommons.org/licenses/by-nc-nd/4.0/ |
| Type: | article |
| URI: | http://hdl.handle.net/2115/59569 |
| Appears in Collections: | 工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)
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Submitter: 菊地 竜也
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