HUSCAP logo Hokkaido Univ. logo

Hokkaido University Collection of Scholarly and Academic Papers >
Graduate School of Engineering / Faculty of Engineering >
Peer-reviewed Journal Articles, etc >

Copper(I)-catalyzed carbon-halogen bond-selective boryl substitution of alkyl halides bearing terminal alkene moieties

Files in This Item:
boryl substitution_HUSCAP.pdf276.15 kBPDFView/Open
Please use this identifier to cite or link to this item:http://hdl.handle.net/2115/61453

Title: Copper(I)-catalyzed carbon-halogen bond-selective boryl substitution of alkyl halides bearing terminal alkene moieties
Authors: Iwamoto, Hiroaki Browse this author
Kubota, Koji Browse this author
Yamamoto, Eiji Browse this author
Ito, Hajime Browse this author →KAKEN DB
Keywords: copper-catalyzed borylation
alkoxy diboron reagents
alkylboronic esters
coupling Reactions
room-temperature
aryl Halides
secondary
electrophiles
boration
bromides
Issue Date: 6-May-2015
Publisher: The Royal Society of Chemistry
Journal Title: Chemical communications
Volume: 51
Issue: 47
Start Page: 9655
End Page: 9658
Publisher DOI: 10.1039/c5cc02760h
PMID: 25977952
Abstract: The selective boryl substitution of alkyl halides bearing terminal C=C double bonds has been achieved using a copper(I)/tricyclohexylphosphine or copper(I)/o-diphenylphosphinophenol catalyst. This reaction represents a useful complementary approach to conventional procedures for the hydroboration of C=C double bonds or the borylative cyclization of alkyl halides bearing terminal alkenes.
Type: article (author version)
URI: http://hdl.handle.net/2115/61453
Appears in Collections:工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 伊藤 肇

Export metadata:

OAI-PMH ( junii2 , jpcoar )

MathJax is now OFF:


 

 - Hokkaido University