Copper(I)-catalyzed carbon-halogen bond-selective boryl substitution of alkyl halides bearing terminal alkene moieties


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Please use this identifier to cite or link to this item:http://hdl.handle.net/2115/61453

Title:	Copper(I)-catalyzed carbon-halogen bond-selective boryl substitution of alkyl halides bearing terminal alkene moieties
Authors:	Iwamoto, Hiroaki Browse this author
	Kubota, Koji Browse this author
	Yamamoto, Eiji Browse this author
	Ito, Hajime Browse this author →KAKEN DB
Keywords:	copper-catalyzed borylation
	alkoxy diboron reagents
	alkylboronic esters
	coupling Reactions
	room-temperature
	aryl Halides
	secondary
	electrophiles
	boration
	bromides
Issue Date:	6-May-2015
Publisher:	The Royal Society of Chemistry
Journal Title:	Chemical communications
Volume:	51
Issue:	47
Start Page:	9655
End Page:	9658
Publisher DOI:	10.1039/c5cc02760h
PMID:	25977952
Abstract:	The selective boryl substitution of alkyl halides bearing terminal C=C double bonds has been achieved using a copper(I)/tricyclohexylphosphine or copper(I)/o-diphenylphosphinophenol catalyst. This reaction represents a useful complementary approach to conventional procedures for the hydroboration of C=C double bonds or the borylative cyclization of alkyl halides bearing terminal alkenes.
Type:	article (author version)
URI:	http://hdl.handle.net/2115/61453
Appears in Collections:	工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 伊藤肇

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