|
Hokkaido University Collection of Scholarly and Academic Papers >
Graduate School of Engineering / Faculty of Engineering >
Peer-reviewed Journal Articles, etc >
In situ Infrared Spectroscopy of Iridium Oxide
| Title: | In situ Infrared Spectroscopy of Iridium Oxide |
| Authors: | Lesna, R. O. Browse this author | | Kunimatsu, K. Browse this author | | Ohtsuka, Toshiaki Browse this author →KAKEN DB | | Sato, N. Browse this author |
| Keywords: | iridium compounds | | oxygen compounds | | films | | electrochromism | | infrared spectroscopy |
| Issue Date: | Dec-1987 |
| Publisher: | The Electrochemical Society |
| Journal Title: | J. Electrochemical Society |
| Volume: | 134 |
| Issue: | 12 |
| Start Page: | 3090 |
| End Page: | 3094 |
| Publisher DOI: | 10.1149/1.2100345 |
| Abstract: | The structural change of an electrochemically grown iridium oxide film upon its electrochromic effect has been investigated in 1N H2SO4 and HC104, using in situ electrochemically modulated infrared spectroscopy (EMIRS). Modulation of the main redox couple operating within the film was found to be associated with the appearance of a O-H stretching band at the bleached state, which is similar to that of pseudoböhmite. Likely oxide species at the bleached and the colored states are considered in view of the reported findings. |
| Rights: | © The Electrochemical Society, Inc. 1987. All rights reserved. Except as provided under U.S. copyright law, this work may not be reproduced, resold, distributed, or modified without the express permission of The Electrochemical Society (ECS). The archival version of this work was published in J. Electrochem. Soc. 1987 volume 134, issue 12, 3090-3094 . |
| Type: | article |
| URI: | http://hdl.handle.net/2115/62189 |
| Appears in Collections: | 工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)
|
Submitter: 大塚 俊明
|
