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In situ Infrared Spectroscopy of Iridium Oxide

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J.Electrochem.Soc.134,3090-3094(1987), In situ inftared spectrosc. of iridium--.pdf558.5 kBPDFView/Open
Please use this identifier to cite or link to this item:http://hdl.handle.net/2115/62189

Title: In situ Infrared Spectroscopy of Iridium Oxide
Authors: Lesna, R. O. Browse this author
Kunimatsu, K. Browse this author
Ohtsuka, Toshiaki Browse this author →KAKEN DB
Sato, N. Browse this author
Keywords: iridium compounds
oxygen compounds
films
electrochromism
infrared spectroscopy
Issue Date: Dec-1987
Publisher: The Electrochemical Society
Journal Title: J. Electrochemical Society
Volume: 134
Issue: 12
Start Page: 3090
End Page: 3094
Publisher DOI: 10.1149/1.2100345
Abstract: The structural change of an electrochemically grown iridium oxide film upon its electrochromic effect has been investigated in 1N H2SO4 and HC104, using in situ electrochemically modulated infrared spectroscopy (EMIRS). Modulation of the main redox couple operating within the film was found to be associated with the appearance of a O-H stretching band at the bleached state, which is similar to that of pseudoböhmite. Likely oxide species at the bleached and the colored states are considered in view of the reported findings.
Rights: © The Electrochemical Society, Inc. 1987. All rights reserved. Except as provided under U.S. copyright law, this work may not be reproduced, resold, distributed, or modified without the express permission of The Electrochemical Society (ECS). The archival version of this work was published in J. Electrochem. Soc. 1987 volume 134, issue 12, 3090-3094 .
Type: article
URI: http://hdl.handle.net/2115/62189
Appears in Collections:工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 大塚 俊明

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