Iodofluorination of Alkenes Using IF5-Pyridine-HF


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Title:	Iodofluorination of Alkenes Using IF5-Pyridine-HF
Authors:	Yano, Shohei Browse this author
Authors:	Hara, Shoji Browse this author →KAKEN DB
Keywords:	fluorine
	addition
	stereoselective synthesis
	halogenation
	alkenes
Issue Date:	Sep-2015
Publisher:	Georg Thieme Verlag
Journal Title:	Synthesis-stuttgart
Volume:	47
Issue:	18
Start Page:	2839
End Page:	2843
Publisher DOI:	10.1055/s-0034-1381003
Abstract:	Iodofluorination of alkenes was performed by using IF5-pyridine-HF and a reductant such as potassium iodide or tin powder. The addition of IF to the double bond proceeded with stereo- and regioselectivity. In the reaction with internal alkenes, the trans-addition product was obtained selectively. With terminal alkenes, the addition took place regioselectively to give 1-iodo-2-fluoroalkanes.
Rights:	© 2015 Georg Thieme Verlag KG
Type:	article (author version)
URI:	http://hdl.handle.net/2115/62726
Appears in Collections:	工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 原正治

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