Regioselective Synthesis ofFluorohydrines via SN2-Type Ring-Opening of Epoxideswith TBABF-KHF2


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Please use this identifier to cite or link to this item:http://hdl.handle.net/2115/628

Title:	Regioselective Synthesis ofFluorohydrines via SN2-Type Ring-Opening of Epoxideswith TBABF-KHF2
Authors:	Akiyama, Yuriko Browse this author
	Fukuhara, Tsuyoshi Browse this author
	Hara, Shoji³ Browse this author →KAKEN DB
Authors(alt):	原, 正治³
Keywords:	epoxides
	fluorohydrine
	regioselectivity
	ring-opening
	tetrabutylammonium bifluoride (TBABF)-KHF2
Issue Date:	Aug-2003
Publisher:	Thieme
Journal Title:	Synlett
Volume:	2003
Issue:	10
Start Page:	1530
End Page:	1532
Publisher DOI:	10.1055/s-2003-40865
Abstract:	We found that the ring-opening fluorination of terminal epoxidesusing TBABF-KHF2 proceeds with high selectivity throughthe SN2 mechanism. As TBABF-KHF2 iseasily obtainable, is stable, and can be used in glassware, it canbe a useful reagent for 1-fluoro-2-alkanol synthesis from the terminalepoxides.
Relation:	http://www.thieme-chemistry.com/thieme-chemistry/journals/info/index.shtml
Type:	article (author version)
URI:	http://hdl.handle.net/2115/628
Appears in Collections:	工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 原正治

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