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Planar chiral desymmetrization of a two-layered cyclophane and control of dynamic helicity through the arrangement of two nonstereogenic centers

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Please use this identifier to cite or link to this item:http://hdl.handle.net/2115/63577

Title: Planar chiral desymmetrization of a two-layered cyclophane and control of dynamic helicity through the arrangement of two nonstereogenic centers
Authors: Katoono, Ryo Browse this author
Suzuki, Takanori Browse this author
Issue Date: 17-Nov-2015
Publisher: Royal Society of Chemistry
Journal Title: Chemical communications
Volume: 52
Issue: 5
Start Page: 1029
End Page: 1031
Publisher DOI: 10.1039/c5cc09069e
PMID: 26592752
Abstract: We designed a planar chiral two-layered cyclophane, which is inherently achiral but desymmetrized by the arrangement of two nonstereogenic centers. We demonstrate the control of dynamic helicity that is generated by the helical twisting of two-layered planes in the cyclophane, where methyl and cyclohexylmethyl groups act as directing groups.
Type: article (author version)
URI: http://hdl.handle.net/2115/63577
Appears in Collections:理学院・理学研究院 (Graduate School of Science / Faculty of Science) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 上遠野 亮

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