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Effects of N-heteroaromatic ligands on highly luminescent mononuclear copper(I)-halide complexes

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Title: Effects of N-heteroaromatic ligands on highly luminescent mononuclear copper(I)-halide complexes
Authors: Ohara, Hiroki Browse this author
Kobayashi, Atsushi Browse this author
Kato, Masako Browse this author
Keywords: Copper
Mononuclear complexes
Issue Date: Jul-2015
Publisher: Elsevier
Journal Title: Comptes rendus chimie
Volume: 18
Issue: 7
Start Page: 766
End Page: 775
Publisher DOI: 10.1016/j.crci.2015.03.003
Abstract: A series of mononuclear Cu(I)-halide complexes, [CuX(PPh3)(2)(L)] (X= CI-, Br-, I-; PPh3 = triphenylphosphine; L = pyridine (py), isoquinoline (iq), 1,6-naphthyridine (nap)), were synthesized. The emission color of [CuX(PPh3)2(L)] varies from blue to red by changing the L ligands and the halide ions, and all the complexes exhibit high emission quantum yields (0.16-0.99) in the crystals. The emission studies revealed that the emissive states of [CuX(PPh3)(2)(L)] differ depending on the L ligand. Complexes [CuX(PPh3)(2)(py)] and [CuX(PPh3)2(nap)] mainly emit from the singlet metal-to-ligand charge transfer mixed with the halide-to-ligand charge transfer ((1)(M + X)LCT) state at room temperature. In contrast, emissions from [CuX(PPh3)(2)(iq)] at room temperature originate from both (3)(M + X)LCT and (3)pi pi* states. These results indicate that N-heterodomatic ligands play an important role in the emission properties of mononuclear Cu(I)-halide complexes. (C) 2015 Academie des sciences. Published by Elsevier Masson SAS. All rights reserved.
Rights: © 2015. This manuscript version is made available under the CC-BY-NC-ND 4.0 license
Type: article (author version)
Appears in Collections:理学院・理学研究院 (Graduate School of Science / Faculty of Science) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 加藤 昌子

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