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Regioselective C-H Borylation of Heteroaromatic Aldimines with Iridium Complexes

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Title: Regioselective C-H Borylation of Heteroaromatic Aldimines with Iridium Complexes
Authors: Sasaki, Ikuo Browse this author
Ikeda, Toshiki Browse this author
Amou, Tatsunosuke Browse this author
Taguchi, Jumpei Browse this author
Ito, Hajime Browse this author
Ishiyama, Tatsuo Browse this author →KAKEN DB
Keywords: iridium
catalysis
borylation
heteroarenes
regioselectivity
aldimines
Issue Date: Jun-2016
Publisher: Georg Thieme Verlag
Journal Title: Synlett
Volume: 27
Issue: 10
Start Page: 1582
End Page: 1586
Publisher DOI: 10.1055/s-0035-1561578
Abstract: An iridium-catalyzed regioselective C-H borylation of pentafluoroaniline-derived heteroaromatic aldimines has been developed. Various heteroaromatic aldimines underwent borylation by bis(pinacolato)diboron to afford the corresponding borylated products in good yields in the presence of an iridium complex formed in situ from bis(cyclooctadienyl)(methoxy)iridium {[Ir(OMe)(cod)](2)} and 1,10-phenanthroline.
Type: article (author version)
URI: http://hdl.handle.net/2115/64699
Appears in Collections:工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 石山 竜生

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