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Luminescent Thin Films Composed of Nanosized Europium Coordination Polymers on Glass Electrodes

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Title: Luminescent Thin Films Composed of Nanosized Europium Coordination Polymers on Glass Electrodes
Authors: Hasegawa, Yasuchika Browse this author →KAKEN DB
Sugawara, Takeshi Browse this author
Nakanishi, Takayuki Browse this author →KAKEN DB
Kitagawa, Yuichi Browse this author
Takada, Makoto Browse this author
Niwa, Akitsugu Browse this author
Naito, Hiroyoshi Browse this author
Fushimi, Koji Browse this author →KAKEN DB
Keywords: coordination complexes
electrochemical deposition
europium
luminescence
thin films
Issue Date: Feb-2016
Publisher: Wiley-Blackwell
Journal Title: ChemPlusChem
Volume: 81
Issue: 2
Start Page: 187
End Page: 193
Publisher DOI: 10.1002/cplu.201500382
Abstract: Luminescent thin films composed of thermostable lanthanide coordination polymers on glass electrodes were prepared using a novel combination of micelle reactions and electrochemical deposition techniques. The micelle-encapsulated luminescent polymers were obtained by the polymerization of [Eu(hfa)(3)] (hfa=hexafluoroacetylacetonate) with bridging phosphine oxide ligands in micelles using a redox-active ferrocenyl-containing surfactant in water. Films were electrochemically deposited on indium tin oxide coated glass electrodes by potentiostatic polarization of micelle-encapsulated Eu-III coordination polymers. The luminescence properties of the electrochemically deposited films were characterized by measuring their emission spectra, emission lifetimes and emission quantum yields.
Rights: This is the accepted version of the following article: Luminescent Thin Films Composed of Nanosized Europium Coordination Polymers on Glass Electrodes. ChemPlusChem, 81(2):187-193., which has been published in final form at http://dx.doi.org/10.1002/cplu.201500382.
Type: article (author version)
URI: http://hdl.handle.net/2115/64706
Appears in Collections:工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 長谷川 靖哉

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