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Luminescent Thin Films Composed of Nanosized Europium Coordination Polymers on Glass Electrodes
| Title: | Luminescent Thin Films Composed of Nanosized Europium Coordination Polymers on Glass Electrodes |
| Authors: | Hasegawa, Yasuchika Browse this author →KAKEN DB | | Sugawara, Takeshi Browse this author | | Nakanishi, Takayuki Browse this author →KAKEN DB | | Kitagawa, Yuichi Browse this author | | Takada, Makoto Browse this author | | Niwa, Akitsugu Browse this author | | Naito, Hiroyoshi Browse this author | | Fushimi, Koji Browse this author →KAKEN DB |
| Keywords: | coordination complexes | | electrochemical deposition | | europium | | luminescence | | thin films |
| Issue Date: | Feb-2016 |
| Publisher: | Wiley-Blackwell |
| Journal Title: | ChemPlusChem |
| Volume: | 81 |
| Issue: | 2 |
| Start Page: | 187 |
| End Page: | 193 |
| Publisher DOI: | 10.1002/cplu.201500382 |
| Abstract: | Luminescent thin films composed of thermostable lanthanide coordination polymers on glass electrodes were prepared using a novel combination of micelle reactions and electrochemical deposition techniques. The micelle-encapsulated luminescent polymers were obtained by the polymerization of [Eu(hfa)(3)] (hfa=hexafluoroacetylacetonate) with bridging phosphine oxide ligands in micelles using a redox-active ferrocenyl-containing surfactant in water. Films were electrochemically deposited on indium tin oxide coated glass electrodes by potentiostatic polarization of micelle-encapsulated Eu-III coordination polymers. The luminescence properties of the electrochemically deposited films were characterized by measuring their emission spectra, emission lifetimes and emission quantum yields. |
| Rights: | This is the accepted version of the following article: Luminescent Thin Films Composed of Nanosized Europium Coordination Polymers on Glass Electrodes. ChemPlusChem, 81(2):187-193., which has been published in final form at http://dx.doi.org/10.1002/cplu.201500382. |
| Type: | article (author version) |
| URI: | http://hdl.handle.net/2115/64706 |
| Appears in Collections: | 工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)
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Submitter: 長谷川 靖哉
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