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Rhodium-Catalyzed Enantioselective Arylation of Aliphatic Imines

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Title: Rhodium-Catalyzed Enantioselective Arylation of Aliphatic Imines
Authors: Kato, Naoya Browse this author
Shirai, Tomohiko Browse this author
Yamamoto, Yasunori Browse this author →KAKEN DB
Keywords: asymmetric arylation
cationic rhodium
alpha-branched amine
Issue Date: 1-Jun-2016
Publisher: Wiley-Blackwell
Journal Title: Chemistry-A European journal
Volume: 22
Issue: 23
Start Page: 7739
End Page: 7742
Publisher DOI: 10.1002/chem.201601246
PMID: 27119262
Abstract: Chiral rhodium(I)-catalyzed highly enantioselective arylation of aliphatic N-sulfonyl aldimines with arylboronic acids has been developed. This transformation is achieved by the use of a rhodium/bis(phosphoramidite) catalyst to give enantiomerically enriched a-branched amines (up to 99% ee). In addition, this system enables efficient synthesis of (+)-NPS R-568 and Cinacalcet which are calcimimetic agents.
Rights: This is the peer reviewed version of the following article: Chemistry A European journal, 22(23) June 1 2016 Pages 7739–7742 , which has been published in final form at This article may be used for non-commercial purposes in accordance With Wiley-VCH Terms and Conditions for self-archiving.
Type: article (author version)
Appears in Collections:工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 山本 靖典

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