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Selective hydrogenation of acetophenone with supported Pd and Rh catalysts in water, organic solvents, and CO2-dissolved expanded liquids
| Title: | Selective hydrogenation of acetophenone with supported Pd and Rh catalysts in water, organic solvents, and CO2-dissolved expanded liquids |
| Authors: | Fujita, Shin-ichiro Browse this author →KAKEN DB | | Onodera, Yuichi Browse this author | | Yoshida, Hiroshi Browse this author →KAKEN DB | | Arai, Masahiko Browse this author →KAKEN DB |
| Keywords: | hydrogenation | | acetophenone | | solvent effects | | water | | carbon dioxide |
| Issue Date: | 21-Sep-2016 |
| Publisher: | Royal Society of Chemistry |
| Journal Title: | Green chemistry |
| Volume: | 18 |
| Issue: | 18 |
| Start Page: | 4934 |
| End Page: | 4940 |
| Publisher DOI: | 10.1039/c6gc00583g |
| Abstract: | Solvent effects were investigated for selective hydrogenation of acetophenone (AP) with commercial 5% Pd/Al2O3 and 5% Pd/C catalysts using polar and nonpolar solvents. The rate of AP hydrogenation varied with the solvents used in different ways depending on the catalysts used. The highest AP conversion was achieved with water for the two catalysts and the AP conversion was correlated with hydrogen-bond-acceptance (HBA) capability (beta) for Pd/Al2O3 and hydrogen-bond-donation (HBD) capability (alpha) for Pd/C. These trends were the same as the corresponding solvent effects obtained previously with Rh/ Al2O3 and Rh/C catalysts, respectively (Green Chem., 2015, 17, 1877-1883). The influence of solvents on the rate of AP hydrogenation depends on the support materials and not on the metal species. Furthermore, AP hydrogenation was conducted with the four supported noble metal catalysts in different solvents pressurized by CO2 (CO2-dissolved expanded solvents). The influence of CO2 pressurization on the rate of reaction, the product selectivity, and the catalyst life was investigated to know whether or not CO2 molecules could function as a reaction promoter in heterogeneous AP hydrogenation reactions with supported Pd and Rh catalysts in different solvents. |
| Type: | article (author version) |
| URI: | http://hdl.handle.net/2115/67134 |
| Appears in Collections: | 工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)
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Submitter: 荒井 正彦
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