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Reduction of Niobium Oxide Using CaCl2 Melt

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Title: Reduction of Niobium Oxide Using CaCl2 Melt
Authors: Suzuki, Ryosuke O Browse this author →KAKEN DB
Ueda, Isamu Browse this author
Sato, Tatsuya Browse this author
Baba, Masahiko Browse this author
Kikuchi, Tatsuya Browse this author →KAKEN DB
Issue Date: 23-Sep-2012
Publisher: Molten Salt Committee, the Electrochemical Society of Japan
Journal Title: 4th Asian Conference on Molten Salt Chemistry and Technology, and 44th Symposium on Molten Salt Chemistry, Japan
Start Page: 29
End Page: 35
Abstract: Niobium oxide powder was reduced in the molten CaCl2. During the electrolysis of CaO in the melt, calcium deposited is used as the reductanct and the by-product CaO is removed by dissolution into CaCl2 melt. Oxygen is extracted at the graphite anode as CO/CO2 gas evolution. The morphology of the samples was examined and the pulverization mechanism was proposed based on the formation of CaNb2O6. The pulverization was studied via calciothermic reduction of Nb2O5 and NbO without electrolysis and the morphology is compared with that by the electrolysis.
Conference Name: 4th Asian Conference on Molten Salt Chemistry and Technology, and 44th Symposium on Molten Salt Chemistry
Conference Place: Matsushima
Type: proceedings
URI: http://hdl.handle.net/2115/67278
Appears in Collections:工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 鈴木 亮輔

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