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Advancement in Catalytic Asymmetric Hydrogenation of Ketones and Imines, and Development of Asymmetric Isomerization of Allylic Alcohols
| Title: | Advancement in Catalytic Asymmetric Hydrogenation of Ketones and Imines, and Development of Asymmetric Isomerization of Allylic Alcohols |
| Authors: | Ohkuma, Takeshi Browse this author →KAKEN DB | | Arai, Noriyoshi Browse this author |
| Keywords: | asymmetric catalysis | | hydrogenation | | iridium | | isomerization | | ruthenium |
| Issue Date: | Dec-2016 |
| Publisher: | Wiley-Blackwell |
| Journal Title: | Chemical record |
| Volume: | 16 |
| Issue: | 6 |
| Start Page: | 2801 |
| End Page: | 2819 |
| Publisher DOI: | 10.1002/tcr.201600101 |
| PMID: | 27555568 |
| Abstract: | Catalytic asymmetric hydrogenation of ketones through the "metal-ligand cooperative mechanism" has been improved in terms of the efficiency, stereoselectivity, and scope of substrates by varying the arrangement of the catalyst structure and reaction conditions. Imino compounds are also smoothly converted to the optically active amines with appropriate catalysts. This type of catalyst exhibits excellent performance on the asymmetric isomerization of primary allylic alcohols into the optically active aldehydes. This personal account describes recent progress on these topics. |
| Rights: | This is the peer reviewed version of the following article: The Chemical Record. 16(6), Dec 2016, pp.2797–2815, which has been published in final form at http://dx.doi.org/10.1002/tcr.201600101. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving. |
| Type: | article (author version) |
| URI: | http://hdl.handle.net/2115/67735 |
| Appears in Collections: | 工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)
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Submitter: 大熊 毅
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