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Low-temperature synthesis and rational design of nitrides and oxynitrides for novel functional material development

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Title: Low-temperature synthesis and rational design of nitrides and oxynitrides for novel functional material development
Authors: Miura, Akira Browse this author →KAKEN DB
Keywords: NaNH2
DFT calculation
Crystal structure
Electronic structure
X-ray diffraction
Oxygen reduction reaction
Issue Date: 2017
Publisher: 日本セラミックス協会
Journal Title: Journal of the Ceramic Society of Japan
Volume: 125
Issue: 7
Start Page: 552
End Page: 558
Publisher DOI: 10.2109/jcersj2.17055
Abstract: Nitrides and oxynitrides exhibit great potential for novel material development, since their electronic structures can be controlled by tuning the amounts of air-abundant nitrogen and oxygen elements therein. However, the above control methods still need to be developed, and the crystal and electronic structures of the produced nitrides/oxynitrides need to be understood. Herein, I summarize the recent progress in nitride and oxynitride synthesis, highlighting novel low-temperature nitridation of oxides by molten NaNH2, and attempt to rationalize the crystal and electronic structures of nitride and oxynitrides. Moreover, I describe how the catalytic activity of manganese oxynitrides in the oxygen reduction reaction can be enhanced by tuning their nitrogen content and thus their electronic structures.
Type: article
URI: http://hdl.handle.net/2115/68658
Appears in Collections:工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 三浦 章

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