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Cp*Co-III-catalyzed directed C-H trifluoromethylthiolation of 2-phenylpyridines and 6-arylpurines

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Title: Cp*Co-III-catalyzed directed C-H trifluoromethylthiolation of 2-phenylpyridines and 6-arylpurines
Authors: Yoshida, Misaki Browse this author
Kawai, Kentaro Browse this author
Tanaka, Ryo Browse this author
Yoshino, Tatsuhiko Browse this author →KAKEN DB
Matsunaga, Shigeki Browse this author →KAKEN DB
Issue Date: 4-Jun-2017
Publisher: Royal Society of Chemistry
Journal Title: Chemical communications
Volume: 53
Issue: 44
Start Page: 5974
End Page: 5977
Publisher DOI: 10.1039/c7cc03072j
PMID: 28503695
Abstract: Cp*Co-III-catalyzed directed C-H trifluoromethylthiolation using N-trifluoromethylthiodibenzenesulfonimide as an electrophilic SCF3 source is described. 6-Arylpurines, an important structural motif in medicinal chemistry, and 2-phenylpyridines selectively afforded mono-trifluoromethylthiolated products in moderate to good yields using an inexpnsive first-row transition metal catalyst.
Type: article (author version)
Appears in Collections:薬学研究院 (Faculty of Pharmaceutical Sciences) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 松永 茂樹

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