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Hokkaido University Collection of Scholarly and Academic Papers >
Graduate School of Engineering / Faculty of Engineering >
Peer-reviewed Journal Articles, etc >
Generation of Radical Species from Cyclohexane-1,2-dione and the Reaction with Olefins : Preparation of 4,5-Dihydro-7(6H)-benzofuranone Derivatives
| Title: | Generation of Radical Species from Cyclohexane-1,2-dione and the Reaction with Olefins : Preparation of 4,5-Dihydro-7(6H)-benzofuranone Derivatives |
| Authors: | Miura, Masanori Browse this author | | Arai, Noriyoshi Browse this author →KAKEN DB | | Narasaka, Koichi Browse this author |
| Issue Date: | 1998 |
| Publisher: | Chemical Society of Japan |
| Journal Title: | Bulletin of the Chemical Society of Japan |
| Volume: | 71 |
| Issue: | 6 |
| Start Page: | 1437 |
| End Page: | 1441 |
| Publisher DOI: | 10.1246/bcsj.71.1437 |
| Abstract: | Oxidation of cyclohexane-1,2-dione with ammonium hexanitratocerate(IV) (CAN) generates 2,3-dioxocyclohexyl radical, which reacts with electron-rich olefins to afford the corresponding addition products. The adducts thus generated are converted to 4,5-dihydro-7(6H)-benzofuranone by acid treatment. In addition to cyclohexane-1,2-dione, radical species are also generated from cyclopentane-1,2-dione and cycloheptane-1,2-dione. |
| Type: | article |
| URI: | http://hdl.handle.net/2115/70768 |
| Appears in Collections: | 工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)
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Submitter: 新井 則義
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