Generation of α-Nitroalkyl Radicals by Oxidation of Nitronate Anions with Cerium(IV) Ammonium Nitrate and Their Addition Reaction to Electron-Rich Olefins


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Title:	Generation of α-Nitroalkyl Radicals by Oxidation of Nitronate Anions with Cerium(IV) Ammonium Nitrate and Their Addition Reaction to Electron-Rich Olefins
Authors:	Arai, Noriyoshi Browse this author →KAKEN DB
Authors:	Narasaka, Koichi Browse this author
Issue Date:	1995
Publisher:	Chemical Society of Japan
Journal Title:	Chemistry Letters
Volume:	24
Issue:	11
Start Page:	987
End Page:	988
Publisher DOI:	10.1246/cl.1995.987
Abstract:	α-Nitroalkyl radicals are generated by oxidation of nitronate anions with cerium(IV) ammonium nitrate. When the reactions are carried out in the presence of electron-rich olefins, such as silyl enol ethers, intermolecular addition of the radicals proceeds to afford β-nitroketones, which are further converted to α,β-unsaturated ketones in good yield.
Type:	article
URI:	http://hdl.handle.net/2115/70770
Appears in Collections:	工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 新井則義

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