Synthesis of α,β-Unsaturated Carboxylic Acids by Nickel(II)-Catalyzed Electrochemical Carboxylation of Vinyl Bromides


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Please use this identifier to cite or link to this item:http://hdl.handle.net/2115/70908

Title:	Synthesis of α,β-Unsaturated Carboxylic Acids by Nickel(II)-Catalyzed Electrochemical Carboxylation of Vinyl Bromides
Authors:	Kamekawa, Hisato Browse this author
	Kudoh, Hiroki Browse this author
	Senboku, Hisanori Browse this author →KAKEN DB
	Tokuda, Masao Browse this author
Keywords:	Nickel
	Carboxylation
	Vinyl Bromides
Issue Date:	5-Sep-1997
Publisher:	Chemical Society of Japan
Journal Title:	Chemistry Letters
Volume:	26
Issue:	9
Start Page:	917
End Page:	918
Publisher DOI:	10.1246/cl.1997.917
Abstract:	Electrochemical carboxylation of alkyl-substituted vinyl bromides (1a-1g) in the presence of 20 mol% of NiBr2•bpy under an atmospheric pressure of carbon dioxide with a platinum cathode and a magnesium anode gave the corresponding α,β-unsaturated carboxylic acids (2a-2g) in yields of 53-82%.
Type:	article
URI:	http://hdl.handle.net/2115/70908
Appears in Collections:	工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 仙北久典

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