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Stereospecific Electrochemical Carboxylation of β-Bromostyrene by Use of Nickel(II) Catalyst

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Title: Stereospecific Electrochemical Carboxylation of β-Bromostyrene by Use of Nickel(II) Catalyst
Authors: Kuang, Chunxiang Browse this author
Yang, Qing Browse this author
Senboku, Hisanori Browse this author →KAKEN DB
Tokuda, Masao Browse this author
Keywords: electrochemical carboxylation
Issue Date: 5-Apr-2005
Publisher: Chemical Society of Japan
Journal Title: Chemistry Letters
Volume: 34
Issue: 4
Start Page: 528
End Page: 529
Publisher DOI: 10.1246/cl.2005.528
Abstract: Electrochemical carboxylation of (E)- and (Z)-β-bromostyrenes (1) under an atmospheric pressure of carbon dioxide with a platinum cathode and a magnesium anode in the presence of 20 mol % of NiBr2·bpy proceeded with retention of stereochemistry to give the corresponding (E)- or (Z)-cinnamic acids (2). The stereochemical outcome of nickel(II)-catalyzed electrochemical carboxylations was discussed by comparison with predominant formation of a (Z)-isomer from either (E)- or (Z)-β-bromostyrenes.
Type: article
Appears in Collections:工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 仙北 久典

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