Stereospecific Electrochemical Carboxylation of β-Bromostyrene by Use of Nickel(II) Catalyst


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Please use this identifier to cite or link to this item:http://hdl.handle.net/2115/70909

Title:	Stereospecific Electrochemical Carboxylation of β-Bromostyrene by Use of Nickel(II) Catalyst
Authors:	Kuang, Chunxiang Browse this author
	Yang, Qing Browse this author
	Senboku, Hisanori Browse this author →KAKEN DB
	Tokuda, Masao Browse this author
Keywords:	electrochemical carboxylation
Keywords:	Nickel
Issue Date:	5-Apr-2005
Publisher:	Chemical Society of Japan
Journal Title:	Chemistry Letters
Volume:	34
Issue:	4
Start Page:	528
End Page:	529
Publisher DOI:	10.1246/cl.2005.528
Abstract:	Electrochemical carboxylation of (E)- and (Z)-β-bromostyrenes (1) under an atmospheric pressure of carbon dioxide with a platinum cathode and a magnesium anode in the presence of 20 mol % of NiBr2·bpy proceeded with retention of stereochemistry to give the corresponding (E)- or (Z)-cinnamic acids (2). The stereochemical outcome of nickel(II)-catalyzed electrochemical carboxylations was discussed by comparison with predominant formation of a (Z)-isomer from either (E)- or (Z)-β-bromostyrenes.
Type:	article
URI:	http://hdl.handle.net/2115/70909
Appears in Collections:	工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 仙北久典

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