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Infrared Absorption Characteristics of Large-Sized Spherical Aryl-Ether Dendrimers.
| Title: | Infrared Absorption Characteristics of Large-Sized Spherical Aryl-Ether Dendrimers. |
| Authors: | WAKABAYASHI, Yuki Browse this author | | TOKESHI, Manabu Browse this author →KAKEN DB | | HIBARA, Akihide Browse this author | | JIANG, Dong-Lin Browse this author | | AIDA, Takuzo Browse this author | | KITAMORI, Takehiko Browse this author |
| Keywords: | L5AZO |
| Issue Date: | Dec-2000 |
| Publisher: | 日本分析化学会 |
| Journal Title: | Analytical Sciences |
| Volume: | 16 |
| Issue: | 12 |
| Start Page: | 1323 |
| End Page: | 1326 |
| Publisher DOI: | 10.2116/analsci.16.1323 |
| Abstract: | A specially designed experimental setup including a newly constructed KBr cell, a light source, a monochromator and an IR detection system suitable for strictly calibrated IR absorption measurements was constructed in order to elucidate strange phenomenon associated with cis-trans photo-isomerization at 6.26 µm of the azobenzene core located at the center of an aryl-ether dendrimer (L5AZO). The setup used an ordinary Nichrome source to measure the photon flux, irradiation area, and photon absorption rate as exactly as possible. The photon absorption rate was obtained as 1.2×10-3 photons/s·molecule and the absorption cross section of L5AZO molecules was estimated to be 3.1×10-19 cm2/molecule. Since these values of the absorption rate and absorption cross section are not abnormal, the occurrence of a simultaneous five-photon absorption is almost impossible. Therefore, the five-photon absorption and photo-isomerization shown by L5AZO suggested that the multiphoton process was not simultaneous absorption, but possibly a sequential absorption and energy storage until the equivalent energy of isomerization was reached. |
| Type: | article |
| URI: | http://hdl.handle.net/2115/71675 |
| Appears in Collections: | 工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)
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Submitter: 渡慶次 学
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