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Hokkaido University Collection of Scholarly and Academic Papers >
Graduate School of Engineering / Faculty of Engineering >
Peer-reviewed Journal Articles, etc >
Sub-20 nm Microphase-Separated Structures in Hybrid Block Copolymers Consisting of Polycaprolactone and Maltoheptaose
| Title: | Sub-20 nm Microphase-Separated Structures in Hybrid Block Copolymers Consisting of Polycaprolactone and Maltoheptaose |
| Authors: | Isono, Takuya Browse this author | | Otsuka, Issei Browse this author | | Halila, Sami Browse this author | | Borsali, Redouane Browse this author | | Kakuchi, Toyoji Browse this author | | Satoh, Toshifumi Browse this author →KAKEN DB |
| Keywords: | polyester | | oligosaccharide | | block copolymer | | self-assembly |
| Issue Date: | 11-May-2015 |
| Publisher: | フォトポリマー懇話会 |
| Journal Title: | Journal of Photopolymer Science and Technology |
| Volume: | 28 |
| Issue: | 5 |
| Start Page: | 635 |
| End Page: | 642 |
| Publisher DOI: | 10.2494/photopolymer.28.635 |
| Abstract: | The present review summarizes our recent results regarding the synthesis and morphological characterization of sugar-based hybrid block copolymers (BCPs) consisting of maltoheptaose (MH) and poly(ε-caprolactone) (PCL). The AB-, AB2-, AB3-, ABA-, and A2B-type BCPs, in which the A and B blocks are MH and PCL, respectively, were synthesized by combining the living polymerization and click reaction. The in-situ small angle X-ray scattering experiments revealed the formation of ordered microphase-separated structures with a sub-20 nm periodicity. |
| Type: | article |
| URI: | http://hdl.handle.net/2115/71948 |
| Appears in Collections: | 工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)
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Submitter: 佐藤 敏文
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