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Sub-20 nm Microphase-Separated Structures in Hybrid Block Copolymers Consisting of Polycaprolactone and Maltoheptaose

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Title: Sub-20 nm Microphase-Separated Structures in Hybrid Block Copolymers Consisting of Polycaprolactone and Maltoheptaose
Authors: Isono, Takuya Browse this author
Otsuka, Issei Browse this author
Halila, Sami Browse this author
Borsali, Redouane Browse this author
Kakuchi, Toyoji Browse this author
Satoh, Toshifumi Browse this author →KAKEN DB
Keywords: polyester
oligosaccharide
block copolymer
self-assembly
Issue Date: 11-May-2015
Publisher: フォトポリマー懇話会
Journal Title: Journal of Photopolymer Science and Technology
Volume: 28
Issue: 5
Start Page: 635
End Page: 642
Publisher DOI: 10.2494/photopolymer.28.635
Abstract: The present review summarizes our recent results regarding the synthesis and morphological characterization of sugar-based hybrid block copolymers (BCPs) consisting of maltoheptaose (MH) and poly(ε-caprolactone) (PCL). The AB-, AB2-, AB3-, ABA-, and A2B-type BCPs, in which the A and B blocks are MH and PCL, respectively, were synthesized by combining the living polymerization and click reaction. The in-situ small angle X-ray scattering experiments revealed the formation of ordered microphase-separated structures with a sub-20 nm periodicity.
Type: article
URI: http://hdl.handle.net/2115/71948
Appears in Collections:工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 佐藤 敏文

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