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Carbon dioxide and water: An effective multiphase medium for selective hydrogenation of nitriles with a Pd/Al2O3 catalyst

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Title: Carbon dioxide and water: An effective multiphase medium for selective hydrogenation of nitriles with a Pd/Al2O3 catalyst
Authors: Bhosale, Ashvini Browse this author
Yoshida, Hiroshi Browse this author →KAKEN DB
Fujita, Shin-ichiro Browse this author →KAKEN DB
Arai, Masahiko Browse this author →KAKEN DB
Keywords: Multiphase media
Selective hydrogenation
Nitriles
Selectivity control
Water
Issue Date: Dec-2016
Publisher: Elsevier
Journal Title: Journal of CO2 Utilization
Volume: 16
Start Page: 371
End Page: 374
Publisher DOI: 10.1016/j.jcou.2016.09.006
Abstract: The effectiveness of a multiphase medium including CO2 and water was studied for the selective hydrogenation of various nitriles of 2-phenylethyl cyanide (PEC), cinnamonitrile, n-hexanenitrile (HN) and 4-cyanobiphenyl with a conventional Pd/Al2O3 catalyst. Such a multiphase reaction medium was observed to have different impacts changing from one nitrile to another and the selective production of primary amine was achieved with PEC and HN but not with the other nitriles. Possible reasons for the substrate-dependent effects of CO2 and water were discussed.
Rights: © 2016. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/
http://creativecommons.org/licenses/by-nc-nd/4.0/
Type: article (author version)
URI: http://hdl.handle.net/2115/72089
Appears in Collections:工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 荒井 正彦

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