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Highly Enantio- and Diastereoselective Construction of 1,2-Disubstituted Cyclopentane Compounds by Dirhodium(II) Tetrakis[N-phthaloyl-(S)-tert-leucinate]-Catalyzed C–H Insertion Reactions of α-Diazo Esters

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Please use this identifier to cite or link to this item:http://hdl.handle.net/2115/732

Title: Highly Enantio- and Diastereoselective Construction of 1,2-Disubstituted Cyclopentane Compounds by Dirhodium(II) Tetrakis[N-phthaloyl-(S)-tert-leucinate]-Catalyzed C–H Insertion Reactions of α-Diazo Esters
Authors: Minami, Kazushi Browse this author
Tsutsui, Hideyuki Browse this author
Saito, Hiroaki Browse this author
Nambu, Hisanori Browse this author →KAKEN DB
Anada, Masahiro Browse this author →KAKEN DB
Hashimoto, Shunichi6 Browse this author →KAKEN DB
Authors(alt): 穴田, 仁洋6
Keywords: asymmetric catalysis
C–C bond formation
C–H insertion
chiral dirhodium(II) carboxylates
cyclization
α-diazo esters
Issue Date: 19-Oct-2005
Publisher: Wiley-VCH
Journal Title: Advanced Synthesis & Catalysis
Volume: 347
Issue: 11-13
Start Page: 1483
End Page: 1487
Publisher DOI: 10.1002/adsc.200505201
Abstract: A highly enantio- and diastereoselective intramolecular C–H insertion reaction of α-diazo esters has been achieved with the use of dirhodium(II) tetrakis[N-phthaloyl-(S)-tert-leucinate] as a catalyst, providing exclusively cis-2-arylcyclopentane-1-carboxylates in up to 95% ee with no evidence of alkene formation.
Relation: http://www.interscience.wiley.com/
Type: article (author version)
URI: http://hdl.handle.net/2115/732
Appears in Collections:薬学研究院 (Faculty of Pharmaceutical Sciences) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 穴田 仁洋

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