Iridium-Catalyzed Direct Asymmetric Alkylation of Aniline Derivatives using 2-Norbornene


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Please use this identifier to cite or link to this item:http://hdl.handle.net/2115/74509

Title:	Iridium-Catalyzed Direct Asymmetric Alkylation of Aniline Derivatives using 2-Norbornene
Authors:	Shirai, Tomohiko Browse this author
	Okamoto, Takakazu Browse this author
	Yamamoto, Yasunori Browse this author →KAKEN DB
Keywords:	acetanilide
	alkylation
	bicycloalkene
	iridium
	Me-BIPAM
Issue Date:	Jun-2018
Publisher:	Wiley-Blackwell
Journal Title:	Asian journal of organic chemistry
Volume:	7
Issue:	6
Start Page:	1054
End Page:	1056
Publisher DOI:	10.1002/ajoc.201800185
Abstract:	We investigate an efficient and highly enantioselective direct alkylation process for acetanilides that use 2-norbornene with a bis(phosphoramidite)-cationic Ir catalytic system (up to 99% ee). This methodology allows the facile preparation of enantiomerically enriched exo-2-(bicyclo[2.2.1]heptan-2-yl)aniline, which can be readily transformed into other functionalities.
Rights:	This is the peer-reviewed version of the following article: Asian journal of organic chemistry 7(6) pp.1054-1056 , which has been published in final form at https://doi.org/10.1002/ajoc.201800185. This article may be used for non-commercial purposes in accordance with Wiley-VCH Terms and Conditions for Self-Archiving.
Type:	article (author version)
URI:	http://hdl.handle.net/2115/74509
Appears in Collections:	工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 山本靖典

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