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(CaCl2+CaO)溶融塩電解による Ti-6Al-4V 合金の還元合成

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J. Jpn. Inst. Met. 72(12) 921.pdf1.1 MBPDFView/Open
Please use this identifier to cite or link to this item:http://hdl.handle.net/2115/74864

Title: (CaCl2+CaO)溶融塩電解による Ti-6Al-4V 合金の還元合成
Other Titles: Synthesis of Ti-6Al-4V Alloy by the Electrolysis of Molten CaCl2+CaO
Authors: 酒井, 博1 Browse this author
岡, 佑一2 Browse this author
鈴木, 亮輔3 Browse this author →KAKEN DB
Authors(alt): Sakai, Hiroshi1
Oka, Yuichi2
Suzuki, Ryosuke O.3
Keywords: titanium alloy
calciothermic reduction
molten salt
electrolysis
calcium chloride
Issue Date: 1-Dec-2008
Publisher: 日本金属学会
Journal Title: 日本金属学会誌
Journal Title(alt): Journal of the Japan Institute of Metals
Volume: 72
Issue: 12
Start Page: 921
End Page: 927
Publisher DOI: 10.2320/jinstmet.72.921
Abstract: A new process is developed to synthesize the precious alloy directly from the oxide mixtures. This process consists of calciothermic reduction in molten CaCl2 and electrochemical reaction for the recovery of Ca from CaO in the same bath. The molten CaCl2 can dissolve Ca and CaO for complete reaction. The oxide mixture consisting of TiO2, Al2O3, and V2O5 was prepared. Either a simple mixture of oxides or its calcined sample was reduced in the molten CaCl2+CaO. The obtained metallic powder was identified as α-Ti single phase and it contained only about 3000 mass ppm oxygen. Although its metallic composition was close to Ti-6Al-4V, this reduced powder had a broad compositional distribution. This inhomogeneous distribution was improved by the subsequent sintering in argon.
Type: article
URI: http://hdl.handle.net/2115/74864
Appears in Collections:工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 鈴木 亮輔

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