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Phase Transformation of MoSi2 Phase in MoSi2/Mo5Si3 Eutectic Alloy Containing Nb

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Mater. Trans. 40(5) 369.pdf550.82 kBPDFView/Open
Please use this identifier to cite or link to this item:http://hdl.handle.net/2115/75145

Title: Phase Transformation of MoSi2 Phase in MoSi2/Mo5Si3 Eutectic Alloy Containing Nb
Authors: Ueno, Shunkichi Browse this author
Fukui, Toshihiko Browse this author
Tanaka, Ryohei Browse this author
Miura, Seiji Browse this author →KAKEN DB
Mishima, Yoshinao Browse this author
Keywords: niobium
MoSi2
C40 phase
C11b phase
Mo5Si3
transformation
Issue Date: May-1999
Publisher: The Japan Institute of Metals
Journal Title: Materials Transactions, JIM
Volume: 40
Issue: 5
Start Page: 369
End Page: 372
Publisher DOI: 10.2320/matertrans1989.40.369
Abstract: Role of ternary solute element Nb on the C40→C11b phase transformation of the MoSi2 phase in MoSi2/Mo5Si3 eutectic alloys which occurs during heat treatment is discussed in this paper. In the case of stoichiometric MoSi2 a mixture of C40 and C11b phases can be prepared by low-pressure plasma spraying method, in which phase transformation from the metastable C40 to stable C11b is recognized during heating at around 800°C. It is found that the MoSi2 phase in an as-cast eutectic MoSi2/Mo5Si3 alloy with 8.5 at%Nb consist only of metastable C40 phase. The transformation from C40 to C11b in this alloy does not occur by heating up to 1200°C but a portion transforms into C11b by heating at 1400°C. It is shown that the Nb concentration in C40 phase is higher than that in C11b phase in this alloy, which must be relevant to the observed transformation behavior.
Rights: 著作権は日本金属学会にある。利用は著作権の範囲内に限られる、
Type: article
URI: http://hdl.handle.net/2115/75145
Appears in Collections:工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 三浦 誠司

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