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H2Oによるコークスガス化反応の反応機構と速度解析

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Title: H2Oによるコークスガス化反応の反応機構と速度解析
Other Titles: Reaction Mechanism and Kinetic Analysis of Coke Gasification by H2O
Authors: 柏谷, 悦章1 Browse this author →KAKEN DB
石井, 邦宜2 Browse this author
Authors(alt): Kashiwaya, Yoshiaki1
Ishii, Kuniyoshi2
Keywords: metallurgical coke
gasification by H2O
kinetic analysis
reaction mechanism
water gas reaction
water gas shift reaction
Boudouard reaction
Issue Date: 1-Dec-1993
Publisher: 日本鉄鋼協会
Journal Title: 鉄と鋼
Volume: 79
Issue: 12
Start Page: 1311
End Page: 1316
Publisher DOI: 10.2355/tetsutohagane1955.79.12_1311
Abstract: Kinetic analysis of coke gasification by H2O was studied. The reaction mechanism was considered according to the restricting the adsorption site as the carbon having dangling bond at periphery of carbon net plane. The kinds of reactions estimated from reaction mechanism were consistent with the results of gas analysis in gasification experiment. From the reaction mechanism, rate equation which expressed the rate of three kinds of reactions (Water gas reaction I, Water gas reaction II and Boudouard reaction) was proposed. That is, K=ST (k1-W1PH2O+k1-B PCO2) (1+k1-w2) /1+ K4PH2+k5+PH2O+k2PCO+k3PCO2 where ST is the dimensionless concentration of adsorption site (or the number of carbon having dangling bond per a carbon atom). k1-W1, k1-B, k1-W2 are rate contant as promotion term of gasification, corresponding to Water gas reaction I, Boudouard reaction and Water gas reaction II, respectively. k2k5 are rate constant as restriction term by each gases. The results of calculation using the rate constants obtained by kinetic analysis have good agreement with the reaction rate but also the produced gas composition.
Rights: 著作権は日本鉄鋼協会にある
Type: article
URI: http://hdl.handle.net/2115/75665
Appears in Collections:工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 柏谷 悦章

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