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Title: コークスガス化反応に対する鉄添加の影響
Other Titles: Effect of Fe Addition on Coke Gasification
Authors: 柏谷, 悦章1 Browse this author →KAKEN DB
中谷, 庄一2 Browse this author
石井, 邦宜3 Browse this author
Authors(alt): Kashiwaya, Yoshiaki1
Nakaya, Shouichi2
Ishii, Kuniyoshi3
Keywords: metallurgical coke
iron catalyst
kinetic analysis
crystalline size of carbon
reaction mechanism
Issue Date: 1-Jun-1991
Publisher: 日本鉄鋼協会
Journal Title: 鉄と鋼
Volume: 77
Issue: 6
Start Page: 759
End Page: 766
Publisher DOI: 10.2355/tetsutohagane1955.77.6_759
Abstract: Gasification of metallurgical coke to which Fe had been added was studied at 1 000, 1 200, 1 400°C with Ar-CO-CO2 mixtures. The rate of gasification was accelerated by Fe addition. As the results of X-ray diffraction, carbon in coke was roughly classified into two groups, crystal and non-crystal carbon. However, there was no effect of Fe addition on carbon crystal size. Kinetic analysis was carried out on the basis of modified Langmuir-Hinshelwood type rate equation (K=k1ST PCO2/(1+k2PCO+k3PCO2), ST: ratio of total adsorption site to carbon atom), which has been adopted for conventional metallurgical coke. From the rate constants obtained for Fe doped coke, it was found that the high reaction rate was caused by decreasing of k2 and k3, which were inhibition term of reaction by CO and CO2, respectively.
Rights: 著作権は日本鉄鋼協会にある
Type: article
Appears in Collections:工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 柏谷 悦章

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