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炭素の結晶・非結晶の割合を考慮したコークスガス化反応の速度解析

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Title: 炭素の結晶・非結晶の割合を考慮したコークスガス化反応の速度解析
Other Titles: Kinetic Analysis of Coke Gasification Based on Non-crystal/Crystal Ratio of Carbon
Authors: 柏谷, 悦章1 Browse this author →KAKEN DB
石井, 邦宜2 Browse this author
Authors(alt): Kashiwaya, Yoshiaki1
Ishii, Kuniyoshi2
Keywords: metallurgical coke
gasification
kinetic analysis
crystalline size of carbon
reaction mechanism
X-ray diffracion
Issue Date: 1-Aug-1990
Publisher: 日本鉄鋼協会
Journal Title: 鉄と鋼
Volume: 76
Issue: 8
Start Page: 1254
End Page: 1261
Publisher DOI: 10.2355/tetsutohagane1955.76.8_1254
Abstract: Gasification of metallurgical coke was studied at 1000, 1200, 1400°C with Ar-CO-CO2 mixtures. Reaction of coke in blast furnace is dominant from about 900°C. And at the same time, growth of graphite crystal (crystallite) in coke begins to occur from that temperature. In present paper, two types of carbon crystal were classified by means of X-ray diffraction. One is crystallite that contribute to X-ray diffraction, another is noncrystalline carbon that contribute only to background intensity. In this study, reaction model that the two kinds of carbon have different reactivity and react simultaneously and independently, was developed and kinetic analysis was performed. Following results were obtained. (1) Lc increases as function of temperature and there is no influence of reaction. (2) La increases as function of temperature in Ar atmosphere. But in existence of reaction, the size of La is so smaller. From this result, it was considered that the gasification reaction proceeds such as mode of decreasing La. And reaction mechanism combining to characteristic of crystallographic structure is proposed.
Rights: 著作権は日本鉄鋼協会にある
Type: article
URI: http://hdl.handle.net/2115/75668
Appears in Collections:工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 柏谷 悦章

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