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Characteristics of Nano-reactor and Phenomena during Mechanical Milling of Hematite-Graphite Mixture

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Title: Characteristics of Nano-reactor and Phenomena during Mechanical Milling of Hematite-Graphite Mixture
Authors: Kashiwaya, Yoshiaki Browse this author →KAKEN DB
Suzuki, Hiroshi Browse this author
Ishii, Kuniyoshi Browse this author
Keywords: nano-reactor
composite pellet
mechanical milling
ball milling
carbothermic reduction
Issue Date: 15-Dec-2004
Publisher: Iron and Steel Institute of Japan
Journal Title: ISIJ International
Volume: 44
Issue: 12
Start Page: 1975
End Page: 1980
Publisher DOI: 10.2355/isijinternational.44.1975
Abstract: The mechanical milling of hematite and graphite mixture could accelerate the reaction rate extremely, when the mixture after milling was heated up under inert atmosphere. In the previous study, the authors have indicated not only the high reaction rate but also the low starting temperature of the reaction. These phenomena can be understood through the view point of the nano-reactor and the active complex. The nano-reactor was defined in this study through the observation of the milling products by TEM and FE-SEM. The important characteristic of nano-reactor was proposed. Moreover, the phenomena such as the reduction reaction, the phase transformation(formation of an active complex) and the crystalline size degradation occurring in the course of the milling were examined. It was found that the milling of mixture gave a different phenomenon from the single hematite or graphite milling. Furthermore, the atmosphere during the milling affected on the reactivity of the milling product. The existence of oxygen caused the reoxidation of the reduction product which resulted in the different crystalline size after milling.
Rights: 著作権は日本鉄鋼協会にある
Type: article
Appears in Collections:工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 柏谷 悦章

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