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Influence of Additive Amount and Heating Conditions on the Strength of Coke Prepared from Non-Caking Coal

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Title: Influence of Additive Amount and Heating Conditions on the Strength of Coke Prepared from Non-Caking Coal
Authors: Tsubouchi, Naoto Browse this author →KAKEN DB
Naganuma, Ryo Browse this author
Mochizuki, Yuuki Browse this author
Hayashizaki, Hideyuki Browse this author
Shishido, Takahiro Browse this author
Keywords: coal
coke
additives
non-caking coal
heating conditions
coke strength
Issue Date: 15-Aug-2009
Publisher: 一般社団法人 日本鉄鋼協会 (The Iron and Steel Institute of Japan)
Journal Title: ISIJ international
Volume: 59
Issue: 8
Start Page: 1419
End Page: 1426
Publisher DOI: 10.2355/isijinternational.ISIJINT-2018-792
Abstract: In the present study, we prepare several types of specimens from non-caking coal - including specimens in which noncovalent bonds between O-functional groups in coal are cleaved by pyridine and HPC-derived thermoplastic components are introduced into the pores produced by swelling, as well as specimens consisting of physical blends with HPC - and examine the influence of heating conditions and types of caking agents on the production of high-strength coke using a SUS tube. We also investigate the influence of heating conditions and types of caking agents on the strength of coke from pelleted specimens and determine the optimal conditions for producing high-strength coke from non-caking coal. HPC with a wide range of thermoplastic properties is more effective as caking agents than additives containing only low- molecular-weight or high-molecular-weight components. In addition, the strength of the produced coke depends on the amount of the additive, and optimal values of the additive amount are present. It was found that the following heating schedule is effective for producing high-strength coke from non caking coal with added caking agents: First, high-speed heating (20 degrees C/min) to an intermediate temperature in the range 400-600 degrees C, recognized as the thermoplastic temperature range for typical caking coal; then, low-speed heating (3 degrees C/min) to the temperature range of 900-1 000 degrees C. Moreover, we demonstrate that, by increasing the rate of heating in the thermoplastic temperature range, it is possible to reduce the amount of caking agent added.
Type: article
URI: http://hdl.handle.net/2115/75913
Appears in Collections:工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

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