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Effects of Sintering Temperature on Thermoelectric Device of La-Doped Strontium Titanate in the Combination of Combustion Synthesis and Spark Plasma Sintering

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Please use this identifier to cite or link to this item:http://hdl.handle.net/2115/77015

Title: Effects of Sintering Temperature on Thermoelectric Device of La-Doped Strontium Titanate in the Combination of Combustion Synthesis and Spark Plasma Sintering
Authors: Kikuchi, Asami Browse this author
Zhang, Lihua Browse this author →KAKEN DB
Okinaka, Noriyuki Browse this author →KAKEN DB
Tosho, Tsuyoshi Browse this author
Akiyama, Tomohiro Browse this author →KAKEN DB
Keywords: thermoelectric materials
perovskite oxide
combustion synthesis
spark plasma sintering
Issue Date: 1-Nov-2009
Publisher: The Japan Institute of Metals
Journal Title: MATERIALS TRANSACTIONS
Volume: 50
Issue: 11
Start Page: 2675
End Page: 2679
Publisher DOI: 10.2320/matertrans.M2009225
Abstract: Thermoelectric properties of La-doped SrTiO3 were investigated in order to determine the optimum sintering temperature for its fabrication by using a combination of combustion synthesis and spark plasma sintering. Combustion-synthesized samples (Sr1−xLaxTiO3, x=0.08) were subjected to spark plasma sintering at temperatures from 1513 to 1663 K. The average grain size of sintered Sr0.92La0.08TiO3 enlarged as sintering temperature rose up. The maximum average grain size was 23.5 μm for a sintering temperature of 1663 K. The thermoelectric properties of sintered Sr0.92La0.08TiO3 were measured from room temperature to 1073 K. The optimum sintering temperature in the experimental sintering temperature range was 1633 K. Among the samples, the Sr0.92La0.08TiO3 sample sintered at 1633 K showed the maximum power factor of 1.51×10−3 Wm−1K−1 at 375 K. Further, we investigated the effects of pressing direction during sintering on the thermoelectric properties of combustion-synthesized Sr0.92La0.08TiO3. The combustion-synthesized samples were sintered well along the pressing direction during sintering; therefore, the electric conductivity measured along the pressing direction during sintering was more than twice that measured along the direction perpendicular to the pressing direction during sintering. Thus, we concluded that pressing direction during sintering affected the electric property of Sr0.92La0.08TiO3.
Type: article
URI: http://hdl.handle.net/2115/77015
Appears in Collections:工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 沖中 憲之

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