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Nickel-Copper-Catalyzed Hydroacylation of Vinylarenes with Acyl Fluorides and Hydrosilanes
Title: | Nickel-Copper-Catalyzed Hydroacylation of Vinylarenes with Acyl Fluorides and Hydrosilanes |
Authors: | Ueda, Yusuke Browse this author | Iwai, Tomohiro Browse this author →KAKEN DB | Sawamura, Masaya Browse this author →KAKEN DB |
Keywords: | acyl fluorides | cooperative catalysis | copper | hydroacylation | nickel |
Issue Date: | 17-Jul-2019 |
Publisher: | Wiley-Blackwell |
Journal Title: | Chemistry-A European journal |
Volume: | 25 |
Issue: | 40 |
Start Page: | 9410 |
End Page: | 9414 |
Publisher DOI: | 10.1002/chem.201900822 |
Abstract: | The hydroacylation of vinylarenes with acyl fluorides and hydrosilanes was enabled by a synergistic bimetallic Ni/Cu-catalytic system, giving access to the corresponding branched ketone products. The reaction takes place under mild conditions at 25-80 degrees C and tolerates base-sensitive functional groups such as methoxycarbonyl and acetoxy groups. |
Rights: | This is the peer reviewed version of the following article: Nickel‐Copper‐Catalyzed Hydroacylation of Vinylarenes with Acyl Fluorides and Hydrosilanes, which has been published in final form at https://dx.doi.org/10.1002/chem.201900822. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. |
Type: | article (author version) |
URI: | http://hdl.handle.net/2115/78159 |
Appears in Collections: | 理学院・理学研究院 (Graduate School of Science / Faculty of Science) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)
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Submitter: 澤村 正也
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