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Corrosion inhibition effects of metal cations on SUS304 in 0.5 M Cl- aqueous solution

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Title: Corrosion inhibition effects of metal cations on SUS304 in 0.5 M Cl- aqueous solution
Authors: Islam, Md. Saiful Browse this author
Otani, Kyohei Browse this author
Sakairi, Masatoshi Browse this author →KAKEN DB
Keywords: Stainless steel
Passive films
SEM
XPS
EIS
AFM
Issue Date: 1-Aug-2018
Publisher: Elsevier
Journal Title: Corrosion Science
Volume: 140
Start Page: 8
End Page: 17
Publisher DOI: 10.1016/j.corsci.2018.06.028
Abstract: The corrosion characteristics of SUS304 exposed to 0.5 M Cl- aqueous solution containing different metal cations were studied with immersion tests, surface analysis and electrochemical tests. The mechanism of corrosion with metal cations was clarified by the XPS analysis results together with the hard and soft acid and base (HSAB) concept and the passive films structure. It is supposed that metal cations with large hardness make a layer by chemical bonding with the passive films. The passive films are protected by the metal cation layer from Cl- attack, and consequently corrosion reactions are inhibited.
Rights: ©2018. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/
http://creativecommons.org/licenses/by-nc-nd/4.0/
Type: article (author version)
URI: http://hdl.handle.net/2115/79007
Appears in Collections:工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

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