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meso-Diketopyripentaphyrin and Diketopyrihexaphyrin as Macrocyclic Tripyrrinone Ligands for Ni-II Ions

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Title: meso-Diketopyripentaphyrin and Diketopyrihexaphyrin as Macrocyclic Tripyrrinone Ligands for Ni-II Ions
Authors: Mori, Daiki Browse this author
Yoneda, Tomoki Browse this author →KAKEN DB
Suzuki, Masaaki Browse this author
Hoshino, Tyuji Browse this author
Neya, Saburo Browse this author
Keywords: Expanded Porphyrins
Macrocyclic Complexes
NNNO Ligand
Issue Date: 2-Dec-2019
Publisher: Wiley-Blackwell
Journal Title: Chemistry-an asian journal
Volume: 14
Issue: 23
Start Page: 4169
End Page: 4173
Publisher DOI: 10.1002/asia.201901375
Abstract: We report expanded porphyrins with pyridine rings and two neighboring carbonyl groups, which allow Ni-II ions to coordinate to the tripyrrinone-type NNNO coordination structure with Ni-O bonds. The selectivity of tripyrrinone is superior to other pyrrolic or pyridinic cavities of expanded porphyrins. Introduction of alpha-carbonyl pyridine next to the tripyrrolic conjugated structure is a powerful strategy for regioselective metalation of flexible expanded porphyrinoids.
Rights: This is the peer reviewed version of the following article: Daiki Mori, Tomoki Yoneda, Masaaki Suzuki, Masaaki Tyuji Hoshino, Saburo Neya, Saburo meso‐Diketopyripentaphyrin and Diketopyrihexaphyrin as Macrocyclic Tripyrrinone Ligands for NiII Ions, Chemistry An Asian J., which has been published in final form at []. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.
Type: article (author version)
Appears in Collections:工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 米田 友貴

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