Air- and moisture-stable Xantphos-ligated palladium dialkyl complex as a precatalyst for cross-coupling reactions


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Please use this identifier to cite or link to this item:http://hdl.handle.net/2115/80131

Title:	Air- and moisture-stable Xantphos-ligated palladium dialkyl complex as a precatalyst for cross-coupling reactions
Authors:	Takahashi, Rina Browse this author
	Kubota, Koji Browse this author
	Ito, Hajime Browse this author →KAKEN DB
Issue Date:	11-Jan-2020
Publisher:	Royal Society of Chemistry
Journal Title:	Chemical communications
Volume:	56
Issue:	3
Start Page:	407
End Page:	410
Publisher DOI:	10.1039/c9cc06946a
Abstract:	Although xantphos has been employed in a variety of palladium-catalyzed cross-coupling reactions, there has been little progress in developing Xantphos-ligated precatalysts. In this report, we describe a Xantphos-ligated palladium dialkyl complex that acts as a powerful precatalyst for C-N, C-S, and C-C cross-coupling reactions. This precatalyst is air- and moisture stable but can be thermally activated in the absence of external reagents. Additionally, potential catalyst inhibitors are not generated during the precatalyst activation. This complex thus represents a convenient alternative to previously reported classes of Xantphos-ligated precatalysts.
Type:	article (author version)
URI:	http://hdl.handle.net/2115/80131
Appears in Collections:	工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 久保田浩司

OAI-PMH ( junii2 , jpcoar_1.0 )

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